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Solid Earth An interactive open-access journal of the European Geosciences Union

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doi:10.5194/se-2016-156
© Author(s) 2016. This work is distributed
under the Creative Commons Attribution 3.0 License.
Method article
23 Nov 2016
Review status
A revision of this discussion paper is under review for the journal Solid Earth (SE).
Measurement of geologic nitrogen using mass spectrometry, colourimetry, and a newly adapted fluorometry technique
Benjamin W. Johnson1, Natashia Drage1, Jody Spence1, Nova Hanson2, Rana El-Sabaawi2, and Colin Goldblatt1 1School of Earth and Ocean Sciences, University of Victoria, Victoria, BC Canada
2Department of Biology, University of Victoria, Victoria, BC, Canada
Abstract. Long viewed as a mostly noble, atmospheric species, recent work demonstrates that nitrogen in fact cycles throughout the Earth system, including the atmosphere, biosphere, oceans, and solid Earth. Despite this new-found behaviour, more thorough investigation of N in geologic materials is limited due to its low concentration (1 to 10 s ppm) and difficulty in analysis. In addition, N can exist in multiple species (NO3, NH4+, N2, organic-N), and determining which species is actually quantified can be difficult. In rocks and minerals, NH4+ is the most stable form of N over geologic time scales. As such, techniques designed to measure NH4+ can be particularly useful.

We measured a number of geochemical rock standards using three different techniques: mass spectrometry, colourimetry, and fluorometry. The fluorometry approach is a novel adaptation of a technique commonly used in biologic science, applied herein to geologic NH4+. Briefly, NH4+ can be quantified by HF-dissolution, neutralization, addition of a fluorescing reagent, and analysis on a standard fluorometer. We reproduce published values for several rock standards (BCR-2, BHVO-2, and G-2), especially if an additional distillation step is performed. While it is difficult to assess quality of each method, due to lack of international geologic N standards, fluorometry appears better suited to analyzing mineral-bound NH4+ than mass spectrometry, and is a simpler, quicker alternative to colourimetry.

To demonstrate a potential application of fluorometry, we calculated a continental crust N budget based on new measurements. We used glacial tills as a proxy for upper crust and analyzed several poorly constrained rock types (volcanics, mid-crustal xenoliths) to determine that the continental crust contains ∼ 2 × 1018 kg N. This estimate is consistent with recent budget estimates, and shows that fluorometry is appropriate for large-scale questions where high sample throughput is helpful. Lastly, we report the first δ15N values of six rock standards: BCR-2 (1.05 ± 0.4 ‰), BHVO-2 (−0.3 ± 0.2 ‰), G-2 (1.23 ± 1.32 ‰), LKSD-4 (3.59 ± 0.1 ‰), Till-4 (6.33 ± 0.1 ‰), and SY-4 (2.13 ± 0.5 ‰). The need for international geologic N standards is crucial for further investigation of the Earth system N cycle, and we suggest that existing rock standards may be suited to this need.


Citation: Johnson, B. W., Drage, N., Spence, J., Hanson, N., El-Sabaawi, R., and Goldblatt, C.: Measurement of geologic nitrogen using mass spectrometry, colourimetry, and a newly adapted fluorometry technique, Solid Earth Discuss., doi:10.5194/se-2016-156, in review, 2016.
Benjamin W. Johnson et al.
Benjamin W. Johnson et al.
Benjamin W. Johnson et al.

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Short summary
Contrary to canonical notions, recent research suggests that N can cycle throughout the solid Earth over geologic time. Such cycling may directly affect climate and biologic productivity. Due to low concentrations in rocks and minerals, analysis and interpretation are difficult. As such, we adapted a fluorometry technique used in aquatic chemistry for use on geologic samples. We compare fluorometry to mass spectrometry and present discussion of the abundance of N in continental crust.
Contrary to canonical notions, recent research suggests that N can cycle throughout the solid...
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